538-58-9, Name is 1,5-Diphenylpenta-1,4-dien-3-one, belongs to chiral-oxygen-ligands compound, is a common compound. Product Details of 538-58-9In an article, once mentioned the new application about 538-58-9.
Safe cyano(nitro)methylating reagent – Michael addition of cyano-aci-nitroacetate leading to delta-functionalized alpha-nitronitriles
A practical, convenient, and safe cyano(nitro)methylation method was developed, in which cyano-aci-nitroacetate served as a synthetic equivalent of anionic nitroacetonitrile. A control of the single/double Michael additions was achieved, which enabled the synthesis of unsymmetrical double Michael adducts. Moreover, the Michael adducts can be used as precursors of pyridine and naphthyridine frameworks.
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Reference£º
Synthesis and Crystal Structure of a Chiral?C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur¨Cnitrogen¨Coxygen ligand derived from aminothiourea and sodium?D-camphor-¦Â-sulfonate