In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 538-58-9, name is 1,5-Diphenylpenta-1,4-dien-3-one, introducing its new discovery. Safety of 1,5-Diphenylpenta-1,4-dien-3-one
Stereochemical Assignment of the Two Diastereosimeric 4-tert-Butyl-7,11-bisarylspiro<5.5>undecane-1,9-diones Using Two-Dimensional Nuclear Magnetic Resonance Spectroscopy
Phase-transfer catalysed condensation between 4-tert-butylcyclohexanone and bis(benzal)acetone yielded two 4-tert-butyl-7,11-bisarylspiro<5.5>undecane-1,9-dione diastereomers.The stereochemical assignment of these molecules was carried out using two-dimensional (2D) NMR spectroscopy.Combined use of COSY and NOESY spectra of these diastereomers helped in unambiguous and complete proton spin system assignment.In addition, from the application of 2D J-resolved spectra together with the Karplus equation, the exact conformation of the molecules could be established.KEY WORDS Diastereomeric differentiation Spiro annulation PTC double Michael condensation 2D NMR (COSY, NOESY and 2D J-resolved)
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Reference£º
Synthesis and Crystal Structure of a Chiral?C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur¨Cnitrogen¨Coxygen ligand derived from aminothiourea and sodium?D-camphor-¦Â-sulfonate