Category: chiral-oxygen-ligands

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Substances labeled in metabolically stable positions. 9. Synthesis of pyridine by thermal rearrangement of amines containing the C5N structure, published in 1995-02-28, which mentions a compound: 616-43-3, mainly applied to thermal rearrangement amine; pyrrole thermal rearrangement; pyridine thermal rearrangement amine, Name: 3-Methyl-1H-pyrrole.

Thermal rearrangement of N-methylbutylamine, N-methylpyrrole, 4-(N-methylamino)butanol and N-methyl-3-pyrrolidinol produces mixtures of various substances which contain pyridine as the basic structure. Only aromatic systems are stable under the reaction conditions.

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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Synthesis and characterization of non-aggregating octa-substituted azaphthalocyanines bearing bulky phenoxy substituents, published in 2008-09-08, which mentions a compound: 56413-95-7, Name is 5,6-Dichloropyrazine-2,3-dicarbonitrile, Molecular C6Cl2N4, Formula: C6Cl2N4.

The synthesis and characterization of two novel series of octaazaphthalocyanines (AzaPc) bearing bulky phenoxy substituents are described. Target precursors to AzaPcs derivatives were prepared by using a nucleophilic aromatic substitution reaction between sterically hindered phenols (2,6-di-iso-propylphenol and 2,6-diphenylphenol) and 5,6-dichloropyrazine-2,3-dicarbonitrile. UV-vis and 1H NMR analyses confirm that steric isolation of the AzaPcs cores enforced both in the solution and in the solid state. This study explores the effectiveness of the steric factor imposed by the applied bulky phenoxy substituents on the packing behavior of azaphthalocyanines and thereby improving their solubility and photo-phys. properties.

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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate

Product Details of 56413-95-7. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5,6-Dichloropyrazine-2,3-dicarbonitrile, is researched, Molecular C6Cl2N4, CAS is 56413-95-7, about Reaction of 2,3-dichloro-5,6-dicyanopyrazine with enamines and some tertiary amines. Author is Hou, Dongfeng; Oshida, Atsushi; Matsuoka, Masaru.

The reaction of 2,3-dichloro-5,6-dicyanopyrazine with enamines as well as a few tertiary amines as enamine precursors was investigated. Both reactions gave aminovinyl-substituted pyrazine derivatives such as I. The products prepared are all of interest as potential pesticides.

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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: cis-4-Aminocyclohexane carboxylic acid(SMILESS: N[C@H]1CC[C@H](CC1)C(O)=O,cas:3685-23-2) is researched.Product Details of 56413-95-7. The article 《Increasing p-type dye sensitised solar cell photovoltages using polyoxometalates》 in relation to this compound, is published in Physical Chemistry Chemical Physics. Let’s take a look at the latest research on this compound (cas:3685-23-2).

Lindqvist polyoxometalate (POM) additives increase VOC in p-type DSSCs by up to 140%, yielding substantial efficiency gains for poorly matched dyes and redox mediators. For better dye/electrolyte combinations, these gains are typically outweighed by losses in JSC. Charge lifetime and transient IR measurements show that this is due to retardation of both recombination and electron transfer to the mediator, and a pos. shift in the NiO valence band edge. The POMs also show their own, limited sensitizing effect.

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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 56413-95-7, is researched, Molecular C6Cl2N4, about Mixing Chromophores: Donor-Acceptor Dyes with Low-Lying LUMOs and Narrow Band Gaps by Connecting 4-Alkoxythiazoles and Azaacenes, the main research direction is tetraazaanthracene donor acceptor dye.Product Details of 56413-95-7.

The synthesis and characterization of novel donor-acceptor (D-A) type functional dyes is presented. The materials studied are based on the 4-alkoxythiazole structure containing one of three arylamine donor units and one of three acceptor building blocks. The nine dyes were characterized with respect to their photo- and electrochem. properties based on UV/Vis absorption and fluorescence emission spectroscopy, and cyclic voltammetry. D. functional theory calculations were carried out to support these studies. The building blocks used brought their characteristics into the final target structures: the reversible oxidation and electron-donating properties of diarylamines, the high fluorescence quantum yields of 4-alkoxythiazoles, and the low-lying LUMOs of tetraazaanthracenes. Furthermore, by introducing tetraazaanthracenes as the acceptor moiety, narrow band gaps of 1.1 and 0.7 eV were estimated electrochem.

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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《The protonation of pyrroles》. Authors are Chiang, Y.; Whipple, E. B..The article about the compound:3-Methyl-1H-pyrrolecas:616-43-3,SMILESS:CC1=CNC=C1).Category: chiral-oxygen-ligands. Through the article, more information about this compound (cas:616-43-3) is conveyed.

Formation of stable α-protonated salts of pyrrole and methylpyrroles in aqueous H2SO4 is demonstrated by their proton magnetic resonance spectra. The observed rates of deuterium exchange in N-methylpyrrole require, however, that β-protonation of the base occur at the faster rate in concentrated H2SO4 solutions The basicity constant of pyrrole is redetermined as pKa = -3.8, considerably below the currently accepted value, and the variation of the ratio of protonated to unprotonated base with H2SO4 concentrations, while self-consistent within the methylpyrrole series, differs from previously defined class acidity functions. The basicity constants vary with Me substitution in a semi-empirically predictable manner.

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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate

COA of Formula: C5H7N. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 3-Methyl-1H-pyrrole, is researched, Molecular C5H7N, CAS is 616-43-3, about Oxidation of pyrrole by dehaloperoxidase-hemoglobin: chemoenzymatic synthesis of pyrrolin-2-ones. Author is McCombs, Nikolette L.; Smirnova, Tatyana; Ghiladi, Reza A..

The use of oxidoreductases as biocatalysts in the syntheses of functionalized, monomeric pyrroles has been a challenge owing to, among a number of factors, undesired polypyrrole formation. Here, we have investigated the ability of dehaloperoxidase (DHP), the coelomic Hb from the terebellid polychaete Amphitrite ornata, to catalyze the H2O2-dependent oxidation of pyrroles as a new class of substrate for this enzyme. Substrate oxidation was observed for all compounds employed (pyrrole, N-methylpyrrole, 2-methylpyrrole, 3-methylpyrrole and 2,5-dimethylpyrrole) under both aerobic and anaerobic conditions. Using pyrrole as a representative substrate, only a single oxidation product, 4-pyrrolin-2-one, was observed, and notably without formation of polypyrrole. Reactivity could be initiated from all three biol. relevant oxidation states for this catalytic globin: ferric, ferrous and oxyferrous. Isotope labeling studies determined that the O-atom incorporated into the 4-pyrrolin-2-one product was derived exclusively from H2O2, indicative of a peroxygenase mechanism. Consistent with this observation, single- and double-mixing stopped-flow UV-visible spectroscopic studies supported compound I, but not compounds ES or II, as the catalytically-relevant ferryl intermediate involved in pyrrole oxidation Electrophilic addition of the ferryl oxygen to pyrrole is proposed as the mechanism of O-atom transfer. The results demonstrate the breadth of chem. reactivity afforded by dehaloperoxidase, and provide further evidence for establishing DHP as a multifunctional globin with practical applications as a biocatalyst.

There are many compounds similar to this compound(616-43-3)COA of Formula: C5H7N. if you want to know more, you can check out my other articles. I hope it will help you，maybe you’ll find some useful information.

Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: cis-4-Aminocyclohexane carboxylic acid, is researched, Molecular C7H13NO2, CAS is 3685-23-2, about Hydrogenation of ammonium p-aminobenzoate on ruthenium and rhodium catalysts, the main research direction is catalytic hydrogenation ammonium aminobenzoate; benzoate amino ammonium hydrogenation; ruthenium catalysis aminobenzoate hydrogenation; rhodium catalysis aminobenzoate hydrogenation.Synthetic Route of C7H13NO2.

The rate of hydrogenation of aqueous p-H2NC6H4CO2- NH4+ in the presence of 10% Rh/C exceeded that in the presence of 10% Ru/C or 9.5% Ru-0.5% Pd/C, and increased linearly with the pressure at 40-100 atm; the apparent activitation energy at 80-150° was 9-10 kcal/mole. The combined yield of cis- (I) and trans-4-amino-1-cyclohexanecarboxylic acid (II) was 92-3% at 80° and 80 atm, but decreased with increasing temperature owing to thermal decomposition; the II-I ratio was independent of pressure, but increased with the hydrogenation temperature, owing to cis-trans isomerization.

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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 3-Methyl-1H-pyrrole( cas:616-43-3 ) is researched.Formula: C5H7N.Gardini, Gian P. published the article 《Simple oxidation products from 2- and 3-methylpyrrole and hydrogen peroxide》 about this compound( cas:616-43-3 ) in Ateneo Parmense, Sezione 1. Acta Bio-medica, Supplemento. Keywords: pyrrole oxidation; oxidation pyrrole; peroxide pyrrolyl. Let’s learn more about this compound (cas:616-43-3).

2-Methylpyrrole (I) and 3-methylpyrrole (II) were subjected to oxidation with 36% H2O2. Thus, a mixture of I + H2O2 (molar ratio 1:1.4) in EtOH-Et2O was lef t at room temperature 10 days to yield 42% III, m. 154° (decomposition). Similarly, II was oxidized (molar ratio II-H2O2 1:2.5) 24 hr at 10° to yield 53% IV, m. 95-6° (sublimed 85°/0.5 mm). Ir spectral data were given.

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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 5,6-Dichloropyrazine-2,3-dicarbonitrile, is researched, Molecular C6Cl2N4, CAS is 56413-95-7, about Comparison of aggregation properties and photodynamic activity of phthalocyanines and azaphthalocyanines, the main research direction is phthalocyanine preparation aggregation photodynamic property; azaphthalocyanine preparation aggregation photodynamic property.Product Details of 56413-95-7.

Phthalocyanines (Pc) and their aza-analogs azaphthalocyanines (AzaPc) (tetrapyrazinoporphyrazines) with eight n-octylsulfanyl or tert-butylsulfanyl peripheral substituents and different central metals (Mg, Zn, metal-free) were synthesized. Dimerization constants Kd and absorption spectra of pure monomeric and dimeric magnesium complexes in toluene were calculated using series of absorbances at different concentrations The bulky tert-butylsulfanyl substituents were found to be much better inhibitors of aggregation than long alkyl chains. Also Pc are less aggregated in organic solvents then AzaPc, short explanation is given. Singlet oxygen production of Pc and AzaPc was compared using dye-sensitized photooxidation of 1,3-diphenylisobenzofuran in pyridine. Both Pc and AzaPc showed similar activity not dependent on type of peripheral substitution. Zinc complexes of both Pc and AzaPc exceeded the magnesium ones and metal-free dyes in singlet oxygen production approx. twice.

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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate