Synthetic Route of 4254-15-3, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 4254-15-3, Name is (S)-Propane-1,2-diol, molecular formula is C3H8O2. In a Article£¬once mentioned of 4254-15-3
Highly regioselective primary etherification of racemic propane-1,2-diol by the tin(II) bromide-catalyzed reaction with diazo[bis(4-methoxyphenyl)]methane and the resolution of enantiomers with the help of Pseudomonas cepacia lipase
The tin(II) bromide-catalyzed reaction of diazo[bis(4-methoxyphenyl)]methane with racemic propane-1,2-diol in 1,2-dimethoxymethane resulted in the highly regioselective etherification of the primary hydroxyl group. After tritylation of the minor 2-ether, 1-[bis(4-methoxyphenyl)]methoxypropane-2-ol was obtained in pure form. The enantiomeric mono-ethers were resolved by kinetic resolution by transacetylation with the help of Pseudomonas cepacia lipase.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 4254-15-3. In my other articles, you can also check out more blogs about 4254-15-3
Reference£º
Synthesis and Crystal Structure of a Chiral?C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur¨Cnitrogen¨Coxygen ligand derived from aminothiourea and sodium?D-camphor-¦Â-sulfonate