24621-61-2, In an article, published in an article,authors is Burk, Mark J., once mentioned the application of 24621-61-2, Name is (S)-Butane-1,3-diol,molecular formula is C4H10O2, is a conventional compound. this article was the specific content is as follows.
Asymmetric intramolecular hydrosilylation of hydroxyketones
A procedure for the catalytic asymmetric intramolecular hydrosilylation of alpha- and beta-hydroxyketones has been developed. A cationic rhodium (I) catalyst bearing the new chiral diphosphine (R,R)-i-Pr-DuPHOS affords the product diols in up to 93% ee.
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Reference£º
Synthesis and Crystal Structure of a Chiral?C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur¨Cnitrogen¨Coxygen ligand derived from aminothiourea and sodium?D-camphor-¦Â-sulfonate