Electric Literature of 538-58-9, Chemistry is a science major with cience and engineering. The main research directions are chemical synthesis, new energy materials, nano-ceramics, nano-hybrid composite materials, preparation and modification of special coatings. 538-58-9, Name is 1,5-Diphenylpenta-1,4-dien-3-one,introducing its new discovery.
Microwave-assisted stereoselective 1,3-dipolar cycloaddition of C,N-diarylnitrone (i.e., N-(arylmethylidene)benzenamine N-oxide) and bis(arylmethylidene)acetone (=1,5-diarylpenta-1,4-dien-3-one): NMR and crystal analysis of diastereoisomeric bis(isoxazolidines)
Microwave-assisted stereoselective 1,3-dipolar cycloaddition of C,N-diarylnitrones (i.e., N-(arylmethylidene)benzenamine N-oxides) 2 to substituted bis(arylmethylidene)acetones (=1,5-diarylpenta-1,4-dien-3-ones) 1 leading to diastereoisomer pairs of bis-isoxazolidines 3 and 4 in good to excellent yield is described (Scheme2 and Table2). The configuration outcome of the reaction is discussed based on the NMR and X-ray data of the products. Copyright
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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate